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Poly(lactic acid) (PLA) Based Tear Resistant and Biodegradable Flexible Films by Blown Film Extrusion

机译:吹膜挤出法制备的基于聚乳酸(PLA)的抗撕裂和可生物降解的柔性膜

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摘要

Poly(lactic acid) (PLA) was melt mixed in a laboratory extruder with poly(butylene adipate-co-terephthalate) (PBAT) and poly(butylene succinate) (PBS) in the presence of polypropylene glycol di glycidyl ether (EJ400) that acted as both plasticizer and compatibilizer. The process was then scaled up in a semi-industrial extruder preparing pellets having different content of a nucleating agent (LAK). All of the formulations could be processed by blowing extrusion and the obtained films showed mechanical properties dependent on the LAK content. In particular the tearing strength showed a maximum like trend in the investigated composition range. The films prepared with both kinds of blends showed a tensile strength in the range 12–24 MPa, an elongation at break in the range 150–260% and a significant crystallinity.
机译:在聚丙二醇二缩水甘油醚(EJ400)存在下,将聚乳酸(PLA)在实验室挤出机中与聚己二酸丁二酯-对苯二甲酸对苯二甲酸酯(PBAT)和聚丁二酸丁二酯(PBS)熔融混合。既充当增塑剂又充当增容剂。然后在半工业挤出机中按比例放大该方法,以制备具有不同含量的成核剂(LAK)的粒料。可以通过吹塑挤出加工所有制剂,并且所获得的膜显示出取决于LAK含量的机械性能。特别地,在研究的组成范围内,撕裂强度显示出最大的类似趋势。两种共混物制备的薄膜均显示出12-24 MPa的拉伸强度,150-260%的断裂伸长率和明显的结晶度。

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